Half time of spontaneous isomerization of chorismic acid

Value 38 Hours
Organism Generic
Reference Wolfenden R, Snider MJ. The depth of chemical time and the power of enzymes as catalysts. Acc Chem Res. 2001 Dec34(12):938-45. p.940 right column 3rd paragraphPubMed ID11747411
Primary Source Andrews PR, Smith GD, Young IG. Transition-state stabilization and enzymic catalysis. Kinetic and molecular orbital studies of the rearrangement of chorismate to prephenate. Biochemistry. 1973 Aug 28 12(18):3492-8.PubMed ID4731190
Comments Note-halftime of 7 hours for spontaneous chorismate mutation given in p.941 fig.4 Figure link - link
Entered by Uri M
ID 107179